ALDRIDGE GROUP

PUBLICATIONS

Full publication list

 

DOI: 10.1002/chem.201700757

 

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DOI: 10.1039/C6CC08449D

 

Recent publications:

Highly electron rich β-diketiminato systems: Synthesis and coordination chemistry of amino functionalized N-nacnac ligands

D.C.H. Do, A. Keyser, A. V. Protchenko, B. Maitland, I. Pernik, H. Niu, E.L. Kolychev, A Rit, A. Stasch, C. Jones, S. Aldridge

Chem.-Eur. J., 2017, in press (DOI: 10.1002/chem.201700757)

A series of highly electron rich amino-functionalized [N-nacnac]- ligands has been synthesized via two different synthetic strategies and their coordination chemistries compared to standard Nacnac donors. Sn(II) and Yb(II) complexes reveals that the steric profile of the N-substituents exerts a subtle influence over the electronic properties of these novel donors.

Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment

D. Dange, C.P. Sindlinger, S. Aldridge, C. Jones

Chem. Commun., 2017, 53, 149-152 (DOI: 10.1039/C6CC08449D)

In the first of two papers looking at the controlled reduction of boryl-substituted group 13 halides in collaboration with the Jones group, the first examples of boryl substituted aluminylene and gallylene complexes are reported. [(DAB)B(THF)Al{Fe(CO)3(mu-CO)}]2 and [(DAB)BGa{mu-Fe(CO)4}]2 have been prepared by reduction of MX2(THF){B(DAB)} (M = Al or Ga, X = Cl or Br) with K2[Fe(CO)4].

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